Stanford University this week said that its scientists are harnessing nanotechnology to quickly produce ultra-lightweight, bendable batteries and supercapacitors in the form of everyday paper.
“Simply coating a sheet of paper with ink made of carbon nanotubes and silver nanowires makes a highly conductive storage device. Society really needs a low-cost, high-performance energy storage device, such as batteries and simple supercapacitors,” said Yi Cui, assistant professor of materials science and engineering.
Like batteries, capacitors hold an electric charge, but for a shorter period of time. However, capacitors can store and discharge electricity much more rapidly than a battery.
"These nanomaterials are special. They are a one-dimensional structure with very small diameters. The small diameter helps the nanomaterial ink stick strongly to the fibrous paper, making the battery and supercapacitor very durable. The paper supercapacitor may last through 40 000 charge-discharge cycles – at least an order of magnitude more than lithium batteries. The nanomaterials also make ideal conductors because they move electricity along much more efficiently than ordinary conductors,” Mr. Cui said.
Cui had previously created nanomaterial energy storage devices using plastics. His new research shows that a paper battery is more durable because the ink adheres more strongly to paper. What is more, you can crumple or fold the paper battery, or even soak it in acidic or basic solutions, and the performance does not degrade. The flexibility of paper allows for many clever applications.
A paper supercapacitor may be especially useful for applications like electric or hybrid cars, which depend on the quick transfer of electricity. The paper supercapacitor's high surface-to-volume ratio gives it an advantage.
"This technology has potential to be commercialized within a short time. I don't think it will be limited to just energy storage devices. This is potentially a very nice, low-cost, flexible electrode for any electrical device,” said Peidong Yang, professor of chemistry at the University of California-Berkeley.
Cui predicts the biggest impact may be in large-scale storage of electricity on the distribution grid. Excess electricity generated at night, for example, could be saved for peak-use periods during the day. Wind farms and solar energy systems also may require storage.
"The most important part of this paper is how a simple thing in daily life – paper – can be used as a substrate to make functional conductive electrodes by a simple process. It's nanotechnology related to daily life, essentially,” added Mr. Yang.



