In a world where electronics are becoming more pervasive, flexibility is a highly desirable trait, but finding materials with the right mix of performance and manufacturing cost remains a challenge. A team of researchers from the University of Pennsylvania has shown that nanoscale particles of the semiconductor cadmium selenide can be "printed" or "coated" on flexible plastics to form high-performance electronics.

“There have been a lot of electron transport studies on cadmium selenide, but until recently we haven’t been able to get good performance out of them. The new aspect of our research was that we used ligands that we can translate very easily onto the flexible plastic; other ligands are so caustic that the plastic actually melts,” said David Kim, a doctoral student in the department of materials science and engineering in Penn’s School of Engineering and Applied Science.

Because the nanocrystals are dispersed in an ink-like liquid, multiple types of deposition techniques can be used to make circuits. In their study, the researchers used spincoating, where centrifugal force pulls a thin layer of the solution over a surface, but the nanocrystals could be applied through dipping, spraying or ink-jet printing as well.

“We have a performance benchmark in amorphous silicon, which is the material that runs the display in your laptop, among other devices. Here, we show that these cadmium selenide nanocrystal devices can move electrons 22 times faster than in amorphous silicon,” said professor Cherie Kagan from the University of Pennsylvania.

Besides speed, another advantage cadmium selenide nanocrystals have over amorphous silicon is the temperature at which they are deposited. Whereas amorphous silicon uses a process that operates at several hundred degrees, cadmium selenide nanocrystals can be deposited at room temperature and annealed at mild temperatures, opening up the possibility of using more flexible plastic foundations. 

“All of these circuits operate with a couple of volts. If you want electronics for portable devices that are going to work with batteries, they have to operate at low voltage or they won’t be useful,” said Ms. Kagan.

On a flexible plastic sheet a bottom layer of electrodes was patterned using a shadow mask — essentially a stencil — to mark off one level of the circuit. The researchers then used the stencil to define small regions of conducting gold to make the electrical connections to upper levels that would form the circuit. An insulating aluminum oxide layer was introduced and a 30nm layer of nanocrystals was coated from solution. Finally, electrodes on the top level were deposited through shadow masks to ultimately form the circuits.

Using this process, the researchers built three kinds of circuits to test the nanocrystals performance for circuit applications: an inverter, an amplifier and a ring oscillator.

“An inverter is the fundamental building block for more complex circuits. We can also show amplifiers, which amplify the signal amplitude in analog circuits, and ring oscillators, where ‘on’ and ‘off’ signals are properly propagating over multiple stages in digital circuits,” said Yuming Lai, a doctoral student in the engineering school’s department of electrical and systems engineering.

With the combination of flexibility, relatively simple fabrication processes and low power requirements, these cadmium selenide nanocrystal circuits could pave the way for new kinds of devices and pervasive sensors, which could have biomedical or security applications.