Silicon dioxide, or sand, makes up about 40% of the earth's crust, but the industrial method for converting sand into crystalline silicon, a vital element of computer chips, is expensive and has a major environmental impact due to the extreme processing conditions. A new way of making crystalline silicon, developed by University of Michigan (UM) researchers, could make this crucial ingredient of computers and solar cells much cheaper and greener.

"The crystalline silicon in modern electronics is currently made through a series of energy-intensive chemical reactions with temperatures in excess of 2000° Fahrenheit (1093.3°C) that produces a lot of carbon dioxide," said Stephen Maldonado, professor of chemistry and applied physics at UM.

Recently, professor Maldonado and chemistry graduate students Junsi Gu and Eli Fahrenkrug discovered a way to make silicon crystals directly at just 180°F (82.2°C), the internal temperature of a cooked turkey. When water is super-saturated with sugar, that sugar can spontaneously form crystals, popularly known as rock candy.

"Instead of water, we are using liquid metal, and instead of sugar, we are using silicon," Maldonado said.

^{Liquid metal makes silicon crystals at record low temperatures}

Mr. Maldonado and colleagues made a solution containing silicon tetrachloride and layered it over a liquid gallium electrode. Electrons from the metal converted the silicon tetrachloride into raw silicon, which then dissolved into the liquid metal.

"The liquid metal is the key aspect of our process. Many solid metals can also deliver electrons that transform silicon tetrachloride into disordered silicon, but only metals like gallium can additionally serve as liquids for silicon crystallization without additional heat," explained the professor.

The researchers reported dark films of silicon crystals accumulating on the surfaces of their liquid gallium electrodes. So far, the crystals are very small, about 1/2000^th of a millimeter in diameter, but Mr. Maldonado hopes to improve the technique and make larger silicon crystals, tailored for applications such as converting light energy to electricity or storing energy. The team is exploring several variations on the process, including the use of other low-melting-point metal alloys.

^{An electron microscope image shows the pure silicon crystals, generated with the new greener technique}

If the approach proves viable, the implications could be huge, especially for the solar energy industry. Crystalline silicon is presently the most-used solar energy material, but the cost of silicon has driven many researchers to actively seek alternative semiconductors.

"It is too premature to estimate precisely how much the process could lower the price of silicon, but the potential for a scalable, dramatically less expensive and more environmentally benign process is there. The dream ultimately is to go from sand to crystalline silicon in one step. There's no fundamental law that says this can't be done," said Stephen Maldonado.

The university is pursuing patent protection for the intellectual property and is seeking commercialization partners to help bring the technology to market.

Tags: Semiconductor